The wide range of fascinating properties observed in complex oxide continue to attract great interest such as ferro-, piezo- and pyroelectricity. Such richness arises from a strong interaction between the charge, orbital, spin, and lattice degrees of freedom. Several strategies have been employed to break the lattice symmetry and expand the range of functionalities. Here, I will show how symmetry breaking offers extraordinary opportunities for observing new properties. In one example [1] I will show our results obtained with a stack of ultrathin defective oxide single-crystal layers (Gd2O3-doped CeO2 (CGO) and Er2O3-stabilized δ-Bi2O3 (ESB)) which yield an extraordinary electrostriction that outperforms any reported electrostrictive materials (organic or inorganic compounds). In another examples [2] I will show another recent discovery illustrating the possibility to induce a large piezoelectric response in centrosymmetric oxides. Such a high piezoelectric response from intrinsically nonpiezoelectric materials has not been observed before in centrosymmetric materials. Recently, new methods have been developed to realized freestanding oxide membranes. Inspired by the recent development in freestanding oxide membrane, and as a final example [3], I will show how we took these results to a whole new and unexplored direction – creating for the first time a new platform for assembling these ultrathin transition-metal oxides (TMOs) freestanding membranes and twisting them into artificial heterointerfaces. This collection of possibilities offers unique opportunities for a wide range of rich world and new functionality of complex oxide and their interfaces.

[1] H. Zhang et al., Nature, 609(7928), 695-700, (2022).

[2] D. -S. Park et al., Science, 375, 653-657 (2022)

[3] Y. Li et al., Adv. Mat., 2203187 (2022)